Comparison of phosphate and phosphate-free detergent additives

  For many years, sodium tripolyphosphate have been an important detergent additive in the field of synthetic detergent. It can improve the cleaning efficiency of surfactants, dispersion, emulsification, dirt compatibilization, chelation of hard calcium and magnesium ions, and generate soluble complex compound to prevent dirt redeposition, buffer alkalinity to improve the rewashing function.

 

  At the same time, phosphorus also contributes to water eutrophication, the proliferation of algae and phytoplankton and marine red tide. It is the culprit responsible for water quality deterioration of rivers and lakes.

 

  The shortcomings of phosphorus-containing detergent make people more inclined to non-phosphorus detergent. There are many non-phosphorus detergent additives, 4A zeolite, sodium metasilicate, crystalline layered sodium disilicate and modified sodium disilicate (MDS), etc.

 

  Property comparisons of these additives are as follows:

 

  ① softened water property:

 

name

MDS

STPP

sodium metasilicate

4A zeolite

35 20min CaCO3 mg/g(product)

352.93

347.60

164

301.40

35 20min MgCO3 mg/g(product)

402.50

251.30

210

77

 

   ②water solubility:

 

name

MDS

Sodium metasilicate

layered disilicate

4Azeolite

STPP

20 solubility

≥80

50

insoluble

insoluble

17

  

       ③decontamination index:

 

name

MDS

STPP

4A zeolite

Standard powder

Decontamination index

1.46

1.50

1.31

1.00

  

        Comparing these parameters above, it’s obvious that MDS is more outstanding than the other phosphorus-free additives. Therefore, MDS is a new detergent additive in detergent industry.